Start by preparing your ramekins. Using Three, 8oz ramekins; butter each one and the coat in coco powder to prevent sticking. If using 6oz ramekins you should be able to get 4 cakes.
Over a double boiler melt your chocolate and butter. Set aside to cool.
In a large bowl beat your eggs, egg yolks, sugar on high until thickened and pale in color.
Add the chocolate mixture slowly to your egg mixture while mixing on high.
In a separate bowl mix your flour, salt, cinnamon and chili powder. Mix this into your wet ingredients.
Pour your batter evenly into your prepared ramekins. Bake at 450 degrees F for 14min if you are using 6oz ramekins OR 18 minutes if you are using 8oz ramekins or until the edges are firm but the center is still slightly soft.
Once they come out of the oven let them rest for 20 minutes. Then place a plate on top of your ramekin and flip over. Serve immediately! If you wait too long after this or refrigerate them the molten center will solidify.